sometimes finds in the cavities between the large crystals of this acid some little needle-like crystal forming tufts which are visible as an opaque white mass on the surface of the semitransparent tartaric acid and some- times so much resemble oxalic acid crystals that in the factory of Thann, where they were formerly very abun- dant, they have been taken for oxalic acid crystals and an attempt made to sell them as such. It was soon recognized that they were formed of a particular kind of tartaric acid, giving salts entirely similar to the tar- trates. Mitscherlich who made a comparative study of the known tartrates and of these new salts, which he called paratartrates, found them identical in all their relations. They had the same crystal- line form, the same specific gravity, the same double refraction in the crystalline state, the same angle of the optical axes, the same index of refraction when they were dissolved in the same proportion of water. In short, no method, either physical or chemical, made it possible to distinguish them, and they seemed identical in every respect, save this, that the tartrates acted on polarized light while the paratartrates were entirely without action. Having arrived at this stage in his researches, Pasteur could not fail to be impressed by this apparent contradic- tion. " Mitscherlich was deceived," he said, "in affirm- ing that the crystals of the tartrates and the paratartrates resemble each other. There must be some external differ- ences between them as regards the hemihedral facets. Mitscherlich, preoccupied with his ideas on isomorphism which made much of all the crystalline resemblances between the different forms, would not have seen these differences which he did not seek, but I, who have the preconceived idea of their existence, am in a good posi- tion to find them if they are there." -17- |