rotary power. Like the tartaric acid it carries over this last property into its solutions, whether acid or alkalin, but it presents this unforeseen peculiarity of rotating to the left the plane of polarization when it is in a neutral or an alkalin solution, and on the contrary of rotating it to the right, and to a much greater extent, when it is in an acid solution. In no case, however, has it ceased to be asparagin unless the liquid has been heated or the acids or alkalies have been too concentrated, and it is possible by precipitation to recover it with all the old properties. This proved that the rotary power of a substance did not depend on itself alone and that if the existence of this power had any significance for the ideas on which Pasteur had taken his stand, its meaning and importance were contingent and of a secondary order. I have just said that, in order to leave intact the as- paragin on which one is working, it is necessary not to heat the liquids. Boiled with an alkalin solution, it is transformed into aspartic acid. Does this acid keep any of the rotary power of the asparagin? It is too little soluble in water to make it possible to study it in aqueous solutions. In solution in the alkalies it rotates to the left: in chlorhydric or nitric acid it rotates to the right. Another derivative of asparagin was still more interest- ing to study; viz., the malic acid which one can obtain from it by action of hyponitric acid. This malic acid accompanies tartaric acid in the grape and therefore should arouse curiosity. Experiment shows that in regard to the rotary power it behaves a little like tartaric acid, and that it sometimes even recalls it so much in its properties that one is tempted to suppose for the two acids origin from a common atomic grouping. Never- theless, in their ensemble, the phenomena presented by malic acid and the malates are more complicated than those of tartaric acid and the tartrates. In the latter -21- |